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In-situ impedance spectroscopy of layer-by-layer self-assembly of polyelectrolytes

TitleIn-situ impedance spectroscopy of layer-by-layer self-assembly of polyelectrolytes
Publication TypeConference Paper
Year of Publication2012
AuthorsPrashanth, GR, Murali, P, Varma, MM, Bhat, N
Conference NameEmerging Electronics (ICEE), 2012 International Conference on
Date PublishedDec
KeywordsBiological system modeling, Biosensors, Capacitors, electrochemical electrodes, electrochemical impedance spectroscopy, in-situ impedance spectroscopy, interdigitated capacitors, layer-by-layer self-assembly, Medical diagnostic imaging, PAH-PAA biIayers, poly(acrylic acid), poly(allylamine hydrochloride), polyelectrolyte binding electrical equivalent, polymer electrolytes, self-assembly
Abstract

In-situ impedance spectroscopy of layer-by-layer self-assembly of weak polyelectrolytes is presented. Interdigitated capacitors with active area of 1×1 mm2 and electrode spacing of 5 μm are fabricated and used for this purpose. Measurement results indicate that the impedance decreases with increase in number of polyelectrolyte layers. About 2.5% of relative change in magnitude of impedance at 104.7 KHz is seen for four bi-layers of Poly(Allylamine Hydrochloride) (PAH)/Poly(Acrylic acid) (PAA). An electrical equivalent for polyelectrolyte binding is obtained.

DOI10.1109/ICEmElec.2012.6636250